Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8.

نویسندگان

  • O V Magdysyuk
  • F Adams
  • H-P Liermann
  • I Spanopoulos
  • P N Trikalitis
  • M Hirscher
  • R E Morris
  • M J Duncan
  • L J McCormick
  • R E Dinnebier
چکیده

An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.

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عنوان ژورنال:
  • Physical chemistry chemical physics : PCCP

دوره 16 43  شماره 

صفحات  -

تاریخ انتشار 2014